N-(3-Chlorobenzoyl)-2-methylbenzenesulfonamide
نویسندگان
چکیده
In the title compound, C(14)H(12)ClNO(3)S, the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. Further, the C=O bond and the meta-Cl atom in the benzoyl ring are also anti to each other. The dihedral angle between the sulfonyl and the benzoyl benzene rings is 72.4 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds, forming inversion dimers.
منابع مشابه
N-(2-Chlorobenzoyl)-4-methylbenzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the C=O bond is syn to the Cl substituent in the adjacent benzene ring. The C-S-N-C torsion angle is -80.6 (6)°. The chloro-benzoyl ring is disordered and was refined using a split model [occupancy ratio 0.537 (3):0.463 (3)]. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming inversion dimers.
متن کاملN-(4-Chlorobenzoyl)-4-methylbenzenesulfonamide
The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol-ecules. The dihedral angles between the two aromatic rings in each mol-ecule are 81.0 (1) and 76.3 (1)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds.
متن کاملN-(4-Chlorobenzoyl)-2-methylbenzenesulfonamide
The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol-ecules. The conformations of the N-C bonds in the C-SO(2)-NH-C(O) segments have gauche torsions with respect to the S=O bonds. The mol-ecules are twisted at the S atoms with torsion angles of -54.2 (2) and 63.8 (2)° in the two mol-ecules. The dihedral angles between the sulfonyl benzene rings and the -SO...
متن کامل1-(2-Chlorobenzoyl)-3-(2,3-dimethylphenyl)thiourea
The dihedral angle between the two phenyl groups in the title compound, C16H15ClN2OS, is 14.88 (4)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, pairs of N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.
متن کاملN-(3-Chlorobenzoyl)-3-nitrobenzenesulfonamide
In the title compound, C(13)H(9)ClN(2)O(5)S, the dihedral angle between the two benzene rings is 83.5 (1)°. In the crystal, mol-ecules are linked via N-H⋯O(S) hydrogen bonds into helical chains running along the b axis.
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